V.E.N.O.M. threatens an old man for the half of an emerald arrowhead he has handed to his grandson Daniel, who is fishing with Scott Trakker. Daniel lends the arrowhead to Scott, which brings V.E.N.O.M. down on both boys, and M.A.S.K. helps get Daniel out of a fire. Joined to Mayhem's half, the arrowhead points to the Star Chariot, an alien spacecraft buried near Mesa Verde. Scott and T-Bob are hit by a huge rolling pin and feared lost, then turn up alive with a shared dream of an alien world. V.E.N.O.M. is beaten, and the chariot ends up in a safer home.
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A heist usually asks whether the thieves will get away with the prize; The Star Chariot asks the odder question of whether the prize wants to be stolen. The setup is old-fashioned and efficient. V.E.N.O.M. already holds one half of an emerald arrowhead, and joined to the other half it will point the way to an alien spacecraft buried in the desert a thousand years ago, so V.E.N.O.M. agents corner the old man who kept the missing piece and threaten him until he admits he has passed it to his grandson Daniel. Daniel and his mother are, at that moment, driving Scott Trakker to a creek for a day of fishing.
The script, credited to Jeffrey Scott, saves its best writing for that trip. T-Bob reels in tin cans, one of the boys jokes about coming from a long line of great chiefs and still not catching a fish, and the two swap gifts, with Daniel lending Scott the arrowhead to wear until the setting sun, a tradition between friends. The episode needs the arrowhead around Scott's neck, and it finds a reason that costs nothing and tells us something about both boys: the gesture that makes a friendship is the same one that puts a target on the borrower.
The idea that organises everything after it is that this is a heist in which the object being stolen declines to be stolen. Miles Mayhem wants the ship's propulsion for a new generation of V.E.N.O.M. vehicles, and the team races him toward Mesa Verde National Park. Then the ship takes over the plot. Scott and T-Bob turn up alive after a scare that looked fatal, and in the closing exchange the chariot is said to have found a safer home and may reveal its secrets when all the Miles Mayhems of the world are gone. The thieves never touch the prize; they only open the door for it to leave.
The voices lean on the show's established comedy: Bruce delivers one of his maxims, about a key mattering less than the lock it opens, and Matt turns it into a deduction that the arrowhead must open something far bigger; Dusty offers a canoe, and is told he has an empty teepee for his trouble. Later Bruce's talk of a bird making a new nest sends T-Bob looking for birds.
The standout is the awakening. After the team has sworn that V.E.N.O.M. will pay for what happened to Scott, he turns up alive, announcing that a huge rolling pin hit him and T-Bob and a UFO carried them to an alien planet where they were fixed up. T-Bob insists he had the same dream, and someone points out that robots do not dream. It is the one moment where the episode lets the strangeness of its own premise show, and it does so with a joke rather than an explanation.
The weak point is how cheaply that scare is undone. The episode asks the team to fear the worst and then walks it all back with a dream that two characters happen to share, so the best scene of the second half costs the first half its teeth. The ship's departure is dispatched in a line of dialogue too, which spares V.E.N.O.M. a defeat on screen and denies us a look at what the chariot was for.
Within the opening run it is the odd one out, an episode that spends its energy on mystery rather than on machinery. It is also the one that makes the arrowhead feel like a real object and the boy who wears it feel like a real friend.
- The M.A.S.K. wiki records The Star Chariot as the first appearance of Gloria Baker and Vanessa Warfield, and of their vehicles Shark and Manta.
- The M.A.S.K. wiki credits Sharon Noble with Gloria, Vanessa, the computer, Daniel and Daniel's mother in this episode.
- The M.A.S.K. wiki lists the recording date as September 17, 1985, the day after the date it gives for The Deathstone.
- The M.A.S.K. wiki suggests that the remote control Miles Mayhem uses to summon Switchblade may be the same device Cliff Dagger used to steer the fake UFO in The Deathstone.
- The M.A.S.K. wiki notes that Gloria is first shown at her day job as a driving instructor, and that the car she sits in changes colour between two shots.
- The M.A.S.K. wiki lists three of Bruce Sato's maxims in this episode, including the line that it matters not what a key is made of, so long as it opens the lock.
- The M.A.S.K. wiki lists Firecracker as absent from the mission briefing yet visible in scenes where Shark would be expected, and Buddie Hawks as visible in the final confrontation although he was not part of the mission.
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