Buckshot is Floyd Malloy’s main mask, worn mainly when he pilots Vampire, and it fires ball bearings at opponents and their vehicles. The fan wiki notes the mask is unusual because it is open on top. It lists twelve appearances, from The Spectre of Captain Kidd on.
Kenner first packed it with Vampire. Wikipedia says the mask in the later Vandal release is New Buckshot with a holographic double.
A fan wiki compiled this list of episodes where the mask appears; we have linked each one to our own guide but have not checked every entry against the picture. It runs to 12 episodes.
Powers and episode lists are paraphrased from the pages above; where they disagree, the page says so.
Kenner
Vampire with Floyd Malloy
Kenner
Vandal with Floyd Malloy
Kenner
Floyd Malloy and Vanessa Warfield Two-Pack
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